\r+ r\r>ctz BUREAU OF MINES 

lU 9256 INFORMATION CIRCULAR/1990 



03 73 



Analyses of Natural Gases, 1989 



By J. E. Hamak and Stella Sigler 




U.S. BUREAU OF MINES 
1910-1990 



\ years £ THE MINERALS SOURCE 



**AU OF ^ 



Mission: As the Nation's principal conservation 
agency, the Department of the Interior has respon- 
sibility for most of our nationally-owned public 
lands and natural and cultural resources. This 
includes fostering wise use of our land and water 
resources, protecting our fish and wildlife, pre- 
serving the environmental and cultural values of 
our national parks and historical places, and pro- 
viding for the enjoyment of life through outdoor 
recreation. The Department assesses our energy 
and mineral resources and works to assure that 
their development is in the best interests of all 
our people. The Department also promotes the 
goals of the Take Pride in America campaign by 
encouraging stewardship and citizen responsibil- 
ity for the public lands and promoting citizen par- 
ticipation in their care. The Department also has 
a major responsibility for American Indian reser- 
vation communities and for people who live in 
Island Territories under U.S. Administration. 



Information Circular 9256 



Analyses of Natural Gases, 1989 



By J. E. Hamak and Stella Sigler 



UNITED STATES DEPARTMENT OF THE INTERIOR 
Manuel Lujan, Jr., Secretary 

BUREAU OF MINES 
T S Ary, Director 





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Library of Congress Cataloging in Publication Data: 



Hamak, John E. 

Analyses of natural gases, 1989 / by J. E. Hamak and Stella Sigler. 




60 p. cm. - (Information circular; 9256) 




Includes bibliographical reference* 




Supt. of Docs, no.: I 28.27:9256. 




1. Gas, Natural-United States-Analysis. I. Sigler, Stella. II. Title. 
Information circular (United States. Bureau of Mines); 9256. 


III. Series: 


TN295.U4 [TP350] 622 s-dc20 [665.7] 


90-1950 

CIP 



CONTENTS 



Page 



Abstract 1 

Introduction 2 

Geologic provinces of the Unites States 2 

Tables 8 

Previous publications in this series 60 

ILLUSTRATION 

1. Geologic provinces of the United States 3 

TABLES 

1. Samples from gas and oil wells in the United States 9 

2. Samples from pipelines in the United States 55 



ANALYSIS OF NATURAL GASES, 1989 

By J. E. Hamak 1 and Stella Sigler 2 



ABSTRACT 

This publication contains analyses and related source data for 151 natural gas samples from 19 States. 
Of the total samples, 138 were collected during calendar year 1989. The remainder were collected 
earlier, but releases granting permission to publish were not received until 1989. All samples were 
obtained and analyzed as part of U.S. Bureau of Mines investigations of the occurrences of helium in 
natural gases of countries with free market economies. This survey has been conducted since 1917. The 
analyses published herein were made by mass spectrometer and chromatograph. 

'Petroleum engineer. 

2 Helium resources survey clerk. 

Section of Helium Resources Evaluation, Branch of Helium Resources, Helium Field Operations, U.S. Bureau of Mines, Amarillo, TX. 



INTRODUCTION 



This U.S. Bureau of Mines publication contains analyses 
and related source data for 151 natural gas samples from 
19 States. Of these samples, 138 were collected during 
calendar year 1989; 13 samples were collected earlier, but 
releases granting permission to publish were not received 
until 1989. All samples were obtained and analyzed as 
part of the Bureau's investigations of the occurrences of 
helium in natural gases of countries with free market econ- 
omies. This survey has been conducted since 1917. The 
analyses published herein were made by ihe mass spectro- 
meter and chromatograph. 

The results of these investigations are published annu- 
ally to make the information available to the petroleum 
industry and the general public. Thirty-four publications 
have presented the results of 14,872 gas analyses made 
prior to 1989. The first three bulletins (i-3) 3 contain anal- 
yses and related source data on 5,218 gas samples collected 
from 1917 through 1960; these bulletins have been supple- 
mented annually by information circulars (4-17, 19-24, 26- 
30, 32-34) containing 9,876 analyses of samples collected 
since 1960. 

In 1976, a compilation of the analyses made prior to 
1975 was prepared by the Bureau and published by the 
National Technical Information Service of the U.S. De- 
partment of Commerce (18). This compilation contains 



10,562 analyses of gas samples from gas and oil wells and 
natural gas pipelines in 37 States and 23 foreign countries. 
In 1982, a compilation of analyses made prior to 1981 was 
published (25). The 1982 publication contains 12,554 anal- 
yses of gas samples from gas and oil wells and natural 
gas pipelines in 39 States and 24 foreign countries and 
includes the analyses from the 1976 publication. The latest 
of these compilations was published in 1987 and contains 
14,242 analyses made prior to 1986. The samples were 
taken from wells or pipelines in 40 States and 24 foreign 
countries (31). 

In addition to being in the publications, all analyses 
and related information published through 1989 are avail- 
able on a magnetic tape file. The tape is available for 
$220 from the National Technical Information Service, 
Springfield, VA 22161, phone (703) 487-4650; orders 
should refer to Bureau of Mines tape PB 90-501503. 

The helium survey program is conducted by soliciting 
natural gas samples throughout the United States and 
other countries with free market economies. Without the 
assistance of the petroleum industry, State and Federal 
agencies, and many individuals engaged in oil and gas 
exploration and production, the helium survey in its pres- 
ent scope would not be possible. 



GEOLOGIC PROVINCES OF THE UNITED STATES 



The tables include geologic province codes so each 
sample source can be located within a specific geologic 
province as defined by the Committee on Statistics of 
Drilling of the American Association of Petroleum 
Geologists. 4 These provinces, which are given in the 



Italic numbers in parentheses refer to items in the list of previous 
publications at the end of this report. 

Meyer, R. F. Geologic Provinces Code Map for Computer Use. 
AAPG Bull., v. 54, No. 7, July 1970, pp. 1301-1305. 



following list and shown in figure 1, are delineated by po- 
litical boundaries for convenience and for accommodation 
of data processing equipment. Not all of the provinces 
shown are gas-producing areas, so many of the codes are 
not used in this publication. Since State or Federal own- 
ership is not always known in offshore areas, only one 
code is used for each State. Owing to the lack of infor- 
mation on the location of wells in Alaska, only one code, 
972, is used for all wells. 

The following list and figure 1 are taken from the arti- 
cle cited in footnote 4. 







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Code Province 

100 New England Province 

110 Adirondack Uplift 

120 Atlantic Coast Basin 

130 South Georgia-North Florida Sedimentary Province 

140 South Florida Province 

150 Piedmont-Blue Ridge Province 

160 Appalachian Basin 

200 Warrior Basin 

210 Mid-Gulf Coast Basin 

220 Gulf Coast Basin 

230 Arkla Basin 

240 Desha Basin 

250 Upper Mississippi Embayment 

260 East Texas Basin 

300 Cincinnati Arch 

305 Michigan Basin 

310 Wisconsin Arch 

315 Illinois Basin 

320 Sioux Uplift 

325 Iowa Shelf 

330 Lincoln Anticline 

335 Forest City Basin 

340 Ozark Uplift 

345 Arkoma Basin 

350 South Oklahoma Folded Belt Province 

355 Chautauqua Platform 

360 Anadarko Basin 

365 Cherokee Basin 

370 Nemaha Anticline 

375 Sedgwick Basin 

380 Salina Basin 

385 Central Kansas Uplift 

390 Chadron Arch 

395 Williston Basin 

400 Ouachita Tectonic Belt Province 

405 Kerr Basin 

410 Llano Uplift 

415 Strawn Basin 

420 Fort Worth Syncline 

425 Bend Arch 

430 Permian Basin 

435 Palo Duro Basin 

440 Amarillo Arch 

445 Sierra Grande Uplift 

450 Las Animas Arch 

455 Las Vegas-Raton Basin 

460 Estancia Basin 

465 Orogrande Basin 

470 Pedregosa Basin 

475 Basin-and-Range Province 



Code Province 

500 Sweetgrass Arch 

505 Montana Folded Belt Province 

510 Central Montana Uplift 

515 Powder River Basin 

520 Big Horn Basin 

525 Yellowstone Province 

530 Wind River Basin 

535 Green River Basin 

540 Denver Basin 

545 North Park Basin 

550 South Park Basin 

555 Eagle Basin 

560 San Luis Basin 

565 San Juan Mountain Province 

570 Uinta Uplift 

575 Uinta Basin 

580 San Juan Basin 

585 Paradox Basin 

590 Black Mesa Basin 

595 Piceance Basin 

600 Northern Cascade Range-Okanagan Province 

605 Eastern Columbia Basin 

610 Idaho Mountains Province 

615 Snake River Basin 

620 Southern Oregon Basin 

625 Great Basin Province 

630 Wasatch Uplift 

635 Plateau Sedimentary Province 

640 Mojave Basin 

645 Salton Basin 

650 Sierra Nevada Province 

700 Bellingham Basin 

705 Puget Sound Province 

710 Western Columbia Basin 

715 Klamath Mountains Province 

720 Eel River Basin 

725 Northern Coast Range Province 

730 Sacramento Basin 

735 Santa Cruz Basin 

740 Coastal Basins 

745 San Joaquin Basin 

750 Santa Maria Basin 

755 Ventura Basin 

760 Los Angeles Basin 

765 Capistrano Basin 

800 Heceta Island Area 

805 Keku Islands Area 

810 Gulf of Alaska Basin 

815 Copper River Basin 

820 Cook Inlet Basin 



Code Province 

830 Kandik Province 

835 Kobuk Province 

840 Koyukuk Province 

845 Bristol Bay Basin 

850 Bethel Basin 

855 Norton Basin 

860 Selawik Basin 

863 Yukon Flats Basin 

865 Lower Tanana Basin 

867 Middle Tanana Basin 

870 Upper Tanana Basin 

873 Galena Basin 

875 Innoko Basin 

877 Minchumina Basin 

880 Holitna Basin 

885 Arctic Foothills Province 

890 Arctic Slope Basin 

900 Maine Atlantic offshore-general 

901 Maine Atlantic offshore-State 

902 Maine Atlantic offshore-Federal 

903 New Hampshire Atlantic offshore— general 

904 New Hampshire Atlantic offshore-State 

905 New Hampshire Atlantic offshore-Federal 

906 Massachusetts Atlantic offshore-general 

907 Massachusetts Atlantic offshore-State 

908 Massachusetts Atlantic offshore-Federal 

909 Rhode Island Atlantic offshore— general 

910 Rhode Island Atlantic offshore-State 

911 Rhode Island Atlantic offshore— Federal 

912 Connecticut Atlantic offshore-general 

913 Connecticut Atlantic offshore— State 

914 Connecticut Atlantic offshore-Federal 

915 New York Atlantic offshore— general 

916 New York Atlantic offshore-State 

917 New York Atlantic offshore-Federal 

918 New Jersey Atlantic offshore-general 

919 New Jersey Atlantic offshore— State 

920 New Jersey Atlantic offshore-Federal 

921 Delaware Atlantic offshore-general 

922 Delaware Atlantic offshore-State 

923 Delaware Atlantic offshore-Federal 

924 Maryland Atlantic offshore— general 

925 Maryland Atlantic offshore-State 

926 Maryland Atlantic offshore-Federal 

927 Virginia Atlantic offshore-general 

928 Virginia Atlantic offshore-State 

929 Virginia Atlantic offshore-Federal 

930 North Carolina Atlantic offshore-general 

931 North Carolina Atlantic offshore—State 

932 North Carolina Atlantic offshore-Federal 

933 South Carolina Atlantic offshore-general 

934 South Carolina Atlantic offshore-State 



Code Province 

935 South Carolina Atlantic offshore-Federal 

936 Georgia Atlantic offshore-general 

937 Georgia Atlantic offshore-State 

938 Georgia Atlantic offshore-Federal 

939 Florida Atlantic offshore-general 

940 Florida Atlantic offshore-State 

941 Florida Atlantic offshore-Federal 

942 Florida Gulf of Mexico offshore-general 

943 Florida Gulf of Mexico offshore-State 

944 Florida Gulf of Mexico offshore— Federal 

945 Alabama Gulf of Mexico offshore-general 

946 Alabama Gulf of Mexico offshore-State 

947 Alabama Gulf of Mexico offshore-Federal 

948 Mississippi Gulf of Mexico offshore-general 

949 Mississippi Gulf of Mexico offshore— State 

950 Mississippi Gulf of Mexico offshore-Federal 

951 Louisiana Gulf of Mexico offshore-general 

952 Louisiana Gulf of Mexico offshore-State 

953 Louisiana Gulf of Mexico offshore-Federal 

954 Texas Gulf of Mexico offshore— general 

955 Texas Gulf of Mexico offshore-State 

956 Texas Gulf of Mexico offshore-Federal 

957 California Pacific offshore-general 

958 California Pacific offshore-State 

959 California Pacific offshore-Federal 

960 Oregon Pacific offshore-general 

961 Oregon Pacific offshore-State 

962 Oregon Pacific offshore-Federal 

963 Washington Pacific offshore-general 

964 Washington Pacific offshore-State 

965 Washington Pacific offshore— Federal 

972 Alaska Arctic offshore-general 

973 Alaska Arctic offshore-State 

974 Alaska Arctic offshore-Federal 

975 Alaska Bering Sea offshore— general 

976 Alaska Bering Sea offshore— State 

977 Alaska Bering Sea offshore-Federal 

978 Alaska Pacific offshore-general 

979 Alaska Pacific offshore-State 

980 Alaska Pacific offshore— Federal 

987 Minnesota Lake Superior offshore 

988 Wisconsin Lake Superior offshore 

989 Michigan Lake Superior offshore 

990 Indiana Lake Michigan offshore 

991 Illinois Lake Michigan offshore 

992 Wisconsin Lake Michigan offshore 

993 Michigan Lake Michigan offshore 

994 Michigan Lake Huron offshore 

995 Michigan Lake Erie offshore 
9% Ohio Lake Erie offshore 

997 Pennsylvania Lake Erie offshore 

998 New York Lake Erie offshore 

999 New York Lake Ontario offshore 



TABLES 

The following tables include the results of analyses and related source data from the gas samples, which are divided 
into two groups as follows: 

Table 1— Samples from gas and oil wells in the United States. 

Table 2.-Samples from pipelines in the United States. 

The following list indicates the sources of the samples listed in the tables: 



Source 


Number 

of 
samples 


Tables 


Number 
Source of 

samples 


Tables 


Colorado 

Indiana 

Kansas 


3 
11 

3 

7 

1 

14 

1 

4 

1 
2 


1,2 


Montana .... 
New Mexico . . 
New York . . . 
Oklahoma . . . 
Pennsylvania . . 
Texas 


1 
9 
1 

33 
4 

41 
2 
8 
5 


1,2 


Kentucky 

Mississippi .... 


Utah 




West Virginia . 
Wyoming .... 









All components of the analyses in the tables are reported to the nearest 0.1 pet, except helium, which is reported to 
the nearest 0.01 pet. The word "trace" is used to denote quantities of helium of less than 0.005 pet and quantities of other 
components of less than 0.05 pet. 



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60 



PREVIOUS PUBLICATIONS IN THIS SERIES 



1. Anderson, C. C, and H. H. Hinson. Helium-Bearing Natural 
Gases of the United States. Analyses and Analytical Methods. 
BuMines B 486, 1951, 141 pp. 

2. Boone, W. J., Jr. Helium-Bearing Natural Gases of the United 
States. Analyses and Analytical Methods. Supplement to Bulletin 486. 
BuMines B 576, 1958, 117 pp. 

3. Munnerlyn, R. D., and R. D. Miller. Helium-Bearing Natural 
Gases of the United States. Analyses. Second supplement to Bulletin 
486. BuMines B 617, 1963, 93 pp. 

4. Miller, R. D., and G. P. Norrell. Analyses of Natural Gases of 
the United States, 1961. BuMines IC 8221, 1964, 148 pp. 

5. . Analyses of Natural Gases of the United States, 1962. 

BuMines IC 8239, 1964, 120 pp. 

6. . Analyses of Natural Gases of the United States, 1963. 

BuMines IC 8241, 1965, 102 pp. 

7. Moore, B. J., R D. Miller, and R D. Shrewsbury. Analyses of 
Natural Gases of the United States, 1964. BuMines IC 8302, 1966, 
144 pp. 

8. Moore, B. J., and R D. Shrewsbury. Analyses of Natural Gases 
of the United States, 1965. BuMines IC 8316, 1966, 181 pp. 

9. . Analyses of Natural Gases, 1966. BuMines IC 8356, 1967, 

130 pp. 

10. . Analyses of Natural Gases, 1967. BuMines IC 8395, 1968, 

187 pp. 

11. Cardwell, L. E., and L. F. Benton. Analyses of Natural Gases, 
1968. BuMines IC 8443, 1970, 169 pp. 



12- _ 
134 pp. 
13. 



Analyses of Natural Gases, 1969. BuMines IC 8475, 1970, 

Analyses of Natural Gases, 1970. BuMines IC 8518, 1971, 

Analyses of Natural Gases, 1971. BuMines IC 8554, 1972, 

Analyses of Natural Gases, 1972. BuMines IC 8607, 1973, 
104 pp. 

16. Moore, B. J. Analyses of Natural Gases, 1973. BuMines IC 8658, 
1974, 96 pp. 



130 pp. 

I 4 - _ 
163 pp. 
15. 



17. Moore, B. J. Analyses of Natural Gases, 1974. BuMines IC 8684, 

1975, 122 pp. 

18. . Analyses of Natural Gases, 1917-74. BuMines CP 1-76, 

1976, 889 pp.; NTIS PB 251-202. 
19. 



82 pp. 
20. _ 

94 pp. 
21- _ 

95 pp. 

22. _ 
113 pp. 

23. _ 
100 pp. 

24. _ 
236 pp. 

25. 



Analyses of Natural Gases, 1975. BuMines IC 8717, 1976, 

Analyses of Natural Gases, 1976. BuMines IC 8749, 1977, 

Analyses of Natural Gases, 1977. BuMines IC 8780, 1978, 

Analyses of Natural Gases, 1978. BuMines IC 8810, 1979, 

Analyses of Natural Gases, 1979. BuMines IC 8833, 1980, 

Analyses of Natural Gases, 1980. BuMines IC 8856, 1981, 

Analyses of Natural Gases, 1917-80. BuMines IC 8870, 

1982, 1055 pp. 

26. Miller. R D., and F. R. Hertweck, Jr. Analyses of Natural Gases, 
1981. BuMines IC 8890, 1982, 84 pp. 

27. . Analyses of Natural Gases, 1982. BuMines IC 8942, 1983, 

100 pp. 

28. Hertweck, F. R, Jr., and D. D. Fox. Analyses of Natural Gases, 

1983, BuMines IC 8993, 1984, 127 pp. 

29. Moore, B. J., and J. E. Hamate. Analyses of Natural Gases, 1984. 
BuMines IC 9046, 1985, 102 pp. 

30. Moore, B. J., and S. Sigler. Analyses of Natural Gases, 1985. 
BuMines IC 9096, 1986, 182 pp. 

31. . Analyses of Natural Gases, 1917-85. BuMines IC 9129, 

1987, 1197 pp. 

32. . Analyses of Natural Gases, 1986. BuMines IC 9167, 1988, 

101 pp. 

33. _ 
74 pp. 

34. Hamak, J. E., and S. Sigler. Analyses of Natural Gases, 1988. 
BuMines IC 9225, 1989, 66 pp. 



_. Analyses of Natural Gases, 1987. BuMines IC 9188, 1988, 



405-90 



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